*Acta
Cryst.* (1994). A**50**,
409-410

**Pp. xi + 161. Oxford: International Union of Crystallography/Oxford
Univ. Press, 1992
Price £37.50. ISBN
0-19-855379-X**

This is an opportune time to re-examine the dynamical theory of X-ray diffraction by Ewald. The advent of synchrotrons all over the world has given new impetus to diffraction and scattering studies and with them a new demand for the understanding of basic diffraction theory. This new monograph by the IUCr is therefore timely, offering a concise presentation of Ewald's work for the specialist with a thorough grounding in physics and mathematics. With the rapid growth of X-ray and neutron studies of biological systems, it also would be extremely helpful if the major aspects of the dynamical theory could be presented in a manner understandable to scientists who are nonphysicists. We may hope that someone will now attempt that.

Ewald as a great scientist and gentle person comes to life in this book, with the authors presenting some glimpses into his private life and providing a well rounded presentation of his major scientific contributions.

The monograph begins
with an introductory chapter by Kato on the significance of Ewald's
dynamical theory. This is followed by four contributions constituting
Section *B*, `Ewald as seen by others'.
This section is of particular interest and brings the man to life
- a different person from the formal, rather Germanic, scientist
encountered by the audience of his lectures. Since one of us (JFM) spent
many hours with Ewald, both in Australia and elsewhere, we approached
this book with a deep respect for his brilliance and deep insight into
the physical basis of crystal optics and crystallography. What we had
only glimpsed, and what underlies many of the comments and revelations
in this book, is the humanity of the man - even humility, yet
without any display of false modesty. He knew he was foremost in his
field, but had great tolerance of the difficulties experienced by
others, even senior scientists in crystallography, in understanding his
work. He often came up with appropriate comparisons from other fields,
such as the *Pendellösung* fringes
described well in this monograph. Reading his history, one marvels at
the range of his interests and contributions to science. It is difficult
enough today to try to understand subjects like his dynamical theory, or
the quantum-mechanical approach to the interaction between matter and
radiation; how much more difficult it must have been without the
knowledge of crystal structure that we now possess and the myriad of
related experiments from so many other fields. A lot of his personal
charm and diplomacy was revealed at a NATO conference on direct methods,
organized by Michael Woolfson and held in Parma, Italy. Parma was then a
stronghold of the Communist movement in Italy, with very vocal
representation by the students of the University. Martin Buerger was
lecturing when a group of students entered and disrupted the meeting.
Buerger was furious and looked like providing provocation for a
confrontation, these being only too common at the time. However,
Woolfson, who chaired the session, calmed down Buerger and invited a few
of the troublemakers to talk things over. He managed to propitiate some
of the delegation, but a very pretty and fiery young woman still
protested against `fascists in a NATO-sponsored conference' using their
university. At this stage, Professor Nardelli, host of the conference,
wanted to call in the police, but Ewald interceded and asked if he might
talk to the demonstrators. The organizers could hardly refuse this
request from an elder statesman of science. None of the demonstrators
spoke English, but some of them understood French, and Ewald explained
in fluent French that many of the participants in the meeting were from
non-NATO countries, including the Soviet Union, Hungary, Yugoslavia
*etc*. The students left quietly and
presented no further problems. The conferees continued to use the
university dormitories, but moved the lectures to an hotel. That little
episode was typical of Ewald, demonstrating his ability to identify the
key issue and provide a solution.

Seven contributions,
covering major aspects of Ewald's work and their legacies, are offered
in Section *C*. That by Cruickshank
highlights the origin of the Ewald sphere and the reciprocal lattice as
a result of the dynamical theory and not as the geometrical construction
most of us have accepted as the cornerstone of crystallography. We have
to say that it is easier to comprehend reciprocal-lattice problems from
the geometrical interpretation than from the very complex derivation
that brought Ewald to this singularly striking and so useful result.
Largely unknown to crystallographers is the work by Ewald on lattice
sums and the Madelung constant, a concept widely used in electrostatic
calculations of crystals and briefly described by David Templeton. A
lucid description of X-ray topography, by Andre´ Authier and
Bernard Capelle, describes the importance of the dynamical theory and
demonstrates how basically this theory explains fundamental interactions
of radiation with matter. We draw special attention to the chapter by
Colella on multiple diffraction and the phase problem. This chapter
perhaps describes best the very fundamental nature of the dynamical
theory and its core contribution to much of modern diffraction physics.
One wonders what Ewald would have done if access to modern synchrotrons
and perfect crystals had been possible a few decades ago! Cowley and
Moodie explore how Ewald's two-beam approximation of the propagation of
X-rays through crystals is equally valid for electron diffraction and
how his dynamical theory influenced the foundation of early electron
diffraction theory. This is an elegant exposition of how a well founded
theory can lead to crucial experiments to probe the atomic nature of
matter and provide the theorist with clear-cut data to elucidate and
refine our understanding of it. This section of the monograph also
includes a commentary on Ewald's dynamical theory by Hellmut Juretschke,
who has also provided some of the long-awaited English translations of
Ewald's early papers. This chapter also provides insight into the
concepts underlying the complex nature of Ewald's work, and should be of
particular interest to scientists using diffraction techniques who are
not specialists in diffraction theory, who may shy away from the
formidable complexity of Ewald's mathematical presentation. In the last
chapter of this section, R. K. Bullough and F. Hynne offer an exposition
of the extinction theorem as applied to amorphous matter. This is a
general extension of the dynamical theory to the analysis of dielectric
phenomena and nonlinear optics. The authors point out that `perhaps the
most spectacular feature of the nonlinear extinction theorem is its
possibility for dynamical chaos' - a fact of nature discovered
with Ewald's elegant and all-embracing dynamical theory.

Section
*D* - `Ewald Speaks for Himself'
contains five of his more fundamental papers, including a welcome
translation, by Juretschke, of his trendsetting paper on the
contributions to the theory of the interferences of X-rays in crystals.
The book concludes with a bibliography of Ewald's publications, also
compiled by Juretschke, and useful name and subject indices.

This is a remarkable monograph, and should be a `must-read' study for everyone interested in scattering problems.

**Benno P.
Schoenborn**

*
Life Sciences
Division
Los Alamos National
Laboratory
Los Alamos
NM
87545
USA
*

**J. F.
McConnell
Schoenborn**

*
Department of
Physics
University of New South
Wales
Kensington
New South Wales
Australia
*

**Copyright © 1997 International Union of Crystallography**